Multinuclear silver(i) XPhos complexes with cyclooctatetraene: photochemical C–C bond cleavage of acetonitrile and cyanide bridged Ag cluster formation?
Dalton Transactions Pub Date: 2016-03-01 DOI: 10.1039/C6DT00370B
Abstract
Cationic mono-, di-, tri- and tetra-nuclear silver complexes with Buchwald-type phosphane (XPhos) and cyclooctatetraene (COT) have been synthesized and characterized. Formation of [(XPhos-Ag)n(COT)][SbF6]n (n = 1 and 2) complexes was confirmed by single-crystal X-ray crystallography and multinuclear NMR spectroscopy. Variable-temperature NMR spectroscopy in CD2Cl2 solution shows the fluxionality of the COT ring in the mono-Ag(I) XPhos complex. Fluxionality of COT was also confirmed in the case of the di-Ag(I) XPhos complex by solid-state and solution 31P NMR spectroscopy. The C–C bond cleavage of coordinated acetonitrile [XPhos-Ag(I)-NCCH3] resulting in cyanide bridged Ag cluster formation [(XPhos-Ag)2(μ-CN)n(μ-Ag)n?1] (n = 1, 2, 3 and 4) upon light excitation of [(XPhos-Ag)n(COT)] was confirmed by HRESI-MS, UV-Absorption and HR-TEM.
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Journal Name：Dalton Transactions
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CAS no.: 89640-58-4
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