Lewis acid–surfactant-combined catalyzed synthesis of 4-aminocyclopentenones from glycals in water?
Green Chemistry Pub Date: 2013-08-27 DOI: 10.1039/C3GC41032C
Abstract
4-Aminocyclopentenones were synthesized from readily available glycals and secondary anilines, with the aid of a Lewis acid–surfactant-combined catalyst. The reactions proceeded via a 4π conrotatory electrocyclization, affording the corresponding 4-aminocyclopentenones in good yields with excellent diastereoselectivities.
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Journal Name：Green Chemistry
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