I2-catalyzed oxidative C(sp3)–H/S–H coupling: utilizing alkanes and mercaptans as the nucleophiles?
Chemical Communications Pub Date: 2014-09-26 DOI: 10.1039/C4CC05661B
Abstract
By using alkanes and mercaptans as the nucleophiles with di-tert-butyl peroxide (DTBP) as the oxidant, I2-catalyzed oxidative C(sp3)–H/S–H coupling was achieved. This protocol provides a novel process to construct C(sp3)–S bonds from commercially available hydrocarbons and mercaptans.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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