Microwave-assisted organic acid–base-co-catalyzed tandem Meinwald rearrangement and annulation of styrylepoxides?
Chemical Communications Pub Date: 2020-01-15 DOI: 10.1039/C9CC09262E
Abstract
A novel organic acid–base-co-catalyzed conversion of styrylepoxides into [1,1′-biaryl]-3-carbaldehydes was realized under microwave irradiation. Styrylepoxides first underwent an acid-catalyzed Meinwald rearrangement followed by a tandem base-catalyzed Michael addition, aldol addition, and aromatization sequence to generate [1,1′-biaryl]-3-carbaldehydes.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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