Hydrogen bond-assisted aggregation-induced emission and application in the detection of the Zn(ii) ion?
Dalton Transactions Pub Date: 2016-04-20 DOI: 10.1039/C6DT00265J
Abstract
The compounds of 3-aminopyridine-2-carboxylic acid with K+ (1) and Zn2+ (2) were found to be AIE-active. The AIE behaviours could be attributed to the restriction of intramolecular rotation (RIR) and vibration (RIV) via hydrogen bonds, resulting in rigidity enhancement of the molecules. An AIE-based fluorescence turn on chemosensor for the Zn(II) ion has been developed in aqueous media with high selectivity and sensitivity.
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Journal Name:Dalton Transactions
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CAS no.: 89640-58-4