A permanently porous van der Waals solid by using phosphonate monoester linkers in a metal organic framework??

Chemical Communications Pub Date: 2011-03-09 DOI: 10.1039/C0CC04779A

Abstract

A bis(phosphonatemonoester) is employed as a linker in a Zn(II) metal organic framework. The complex is a layered structure pillared only by vdW interactions between alkyl groups. Nonetheless, permanent pores are formed as confirmed by PXRD and gas sorption analysis.

Graphical abstract: A permanently porous van der Waals solid by using phosphonate monoester linkers in a metal organic framework
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