Ligand control in the photochemical generation of high-valent porphyrin-iron–oxo derivatives?

Chemical Communications Pub Date: 2015-05-18 DOI: 10.1039/C5CC02852C

Abstract

Visible-light irradiation of photo-labile bromate porphyrin-iron(III) salts gave iron(IV)–oxo porphyrin radical cations (compound I model) or the neutral iron(IV)–oxo porphyrin (compound II model), depending on the electronic structure of porphyrin ligands.

Graphical abstract: Ligand control in the photochemical generation of high-valent porphyrin-iron–oxo derivatives
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