Hysteretic carbon dioxide sorption in a novel copper(ii)-indazole-carboxylate porous coordination polymer?

Chemical Communications Pub Date: 2012-10-18 DOI: 10.1039/C2CC37453F

Abstract

The synthesis, structural and gas sorption studies of a porous Cu(II) coordination polymer featuring 1H-indazole-5-carboxylic acid (H2L) are presented. [Cu(HL)2] is a thermally and hydrolytically robust 4-connected 3D coordination polymer of NbO topology and is replete with 1D channels that permit selective and hysteretic sorption of CO2.

Graphical abstract: Hysteretic carbon dioxide sorption in a novel copper(ii)-indazole-carboxylate porous coordination polymer
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