Green solvents for organic thin-film transistor processing?
Journal of Materials Chemistry C Pub Date: 2020-03-19 DOI: 10.1039/D0TC00512F
Abstract
In this study, we explored a wide range of green solvents to process the semiconductor layer TIPS-PEN (6,13-bis(triisopropylsilylethynyl)pentacene), as well as to demonstrate potential generality, using several p- and n-type organic semiconductors, for the fabrication of organic thin-film transistors (OTFTs). Our data demonstrate that several different solvents enable good semiconductor film-forming morphologies and optimized TIPS-PEN TFT mobilities of ～0.5–2 cm2 V?1 s?1, thus surpassing those of toxic chlorinated options. Furthermore, we utilized a green cellulose cinnamate-gate dielectric to fabricate TIPS-PEN OTFTs, where both the semiconductor and the dielectric were processed using green solvents demonstrating the feasibility of a more sustainable OTFT technology.
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Journal Name：Journal of Materials Chemistry C
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CAS no.: 89640-58-4
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