Germanium encapsulated in sulfur and nitrogen co-doped 3D porous carbon as an ultra-long-cycle life anode for lithium ion batteries?

Journal of Materials Chemistry A Pub Date: 2016-11-04 DOI: 10.1039/C6TA08681K

Abstract

Germanium (Ge) has been considered as a promising anode material for Li-ion batteries because of its theoretical capacity (1600 mA h g?1). However, its poor electrochemical performances resulting from the large volume variation during Li–Ge alloy/dealloy processes prevent its practical application. Herein, we designed a 3D core/shell structure by encapsulation of Ge in a sulfur (S) and nitrogen (N) co-doped three-dimensionally (3D) interconnected macroporous carbon matrix (denoted as Ge@S,N-3DPC). The 3D porous structure can not only buffer the volume change during alloy/dealloy processes, but also facilitate the electrolyte to soak in, offering fast ion/electron pathways. What's more, the co-doping of S and N in carbon could introduce more defects and active sites, which can also help to improve the interfacial adsorption and electrochemical behaviors. When used as an anode material for LIBs, the Ge@S,N-3DPC shows excellent electrochemical performances (1000 mA h g?1 at 200 mA g?1), outstanding cycling stability (94% capacity retention after 300 cycles) and high rate capability (358 mA h g?1 at 10 A g?1). This work develops a general strategy to improve the electrochemical performance of these alloy-type electrode materials with huge volume change in the energy storage area.

Graphical abstract: Germanium encapsulated in sulfur and nitrogen co-doped 3D porous carbon as an ultra-long-cycle life anode for lithium ion batteries
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