High-valent oxo-molybdenum and oxo-rhenium complexes as efficient catalysts for X–H (X = Si, B, P and H) bond activation and for organic reductions
Chemical Society Reviews Pub Date: 2012-07-11 DOI: 10.1039/C2CS35155B
Abstract
High-valent oxo-complexes have recently emerged as powerful catalysts for the activation of X–H (X = Si, B, P and H) bonds and for the reduction of several functional groups. This new reactivity represents a complete reversal from the traditional role of these complexes as oxidation catalysts and opened a new research area for high-valent oxo-complexes. This tutorial review highlights the work developed using high-valent oxo-molybdenum and oxo-rhenium complexes as excellent catalysts for X–H (X = Si, B, P and H) bond activation and for organic reductions.
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Journal Name：Chemical Society Reviews
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CAS no.: 89640-58-4
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