Highly selective aluminium-catalysed intramolecular Prins reaction for l-menthol synthesis?
RSC Advances Pub Date: 2014-11-11 DOI: 10.1039/C4RA12470G
Abstract
An aluminium complex bearing 2-cyclohexyl-6-phenylphenol afforded (5R)-n-isopulegol from (R)-citronellal via the intermolecular Prins reaction with an exceptionally high diastereoselectivity. Using this reaction, L-menthol was obtained with an excellent diastereoselectivity.
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Journal Name：RSC Advances
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CAS no.: 89640-58-4
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