Homochiral anionic modification toward the chemical design of organic enantiomeric ferroelectrics?

Chemical Communications Pub Date: 2021-04-20 DOI: 10.1039/D1CC01675J

Abstract

The well-developed design strategy of molecular modification for assembling molecular ferroelectrics mainly focuses on the cations. Herein, by homochiral anionic modification of the non-ferroelectric (quinuclidinium)(HSO4), we designed high-temperature multiaxial organic enantiomeric ferroelectrics, (quinuclidinium)(L- and D-camphorsulfonate). This work paves a new road for precisely constructing excellent molecular ferroelectrics.

Graphical abstract: Homochiral anionic modification toward the chemical design of organic enantiomeric ferroelectrics
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