Incorporation of active metal sites in MOFs via in situ generated ligand deficient metal–linker complexes?
Chemical Communications Pub Date: 2011-10-10 DOI: 10.1039/C1CC14387E
Abstract
Two novel 3D MOFs, namely MOF-647A and MOF-648 (previously unknown trinodal 4-connected net), comprised of Cu ions and pyrazole-3,5-dicarboxylate were synthesized and characterized. A strategy for incorporating open metal sites in MOFs was investigated by utilizing an in situ generated metal–linker complex as a precursor to construct MOF-648.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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