First examples of tri- and tetraphosphametacyclophanes: synthesis and isolation of an unusual hexapalladium complex containing pincer units with Pd–P covalent bonds?
Dalton Transactions Pub Date: 2017-04-21 DOI: 10.1039/C7DT00737J
Abstract
The synthesis of the first examples of tri- and tetraphosphametacyclophanes [m-{–C(O)C5H3N(C(O)PPh)}3 (1) and m-{–C(O)C5H3N(C(O)PPh)}4 (2)] is described. The reaction of 1 with [Pd(η3-C3H5)Cl]2 yielded a rare hexapalladium(II) complex with four Pd–P covalent bonds.
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Journal Name：Dalton Transactions
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