A novel construction of acetamides from rhodium-catalyzed aminocarbonylation of DMC with nitro compounds?
Chemical Communications Pub Date: 2021-01-19 DOI: 10.1039/D1CC00047K
Abstract
Dimethyl carbonate (DMC), an environment-friendly compound prepared from CO2, shows diverse reactivities. In this communication, an efficient procedure using DMC as both a C1 building block and solvent in the aminocarbonylation reaction with nitro compounds has been developed. W(CO)6 acts both a CO source and a reductant here.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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