Formation of (PNP)Rh complexes containing covalent rhodium–zinc bonds in studies of potential Rh-catalysed Negishi coupling?
Chemical Communications Pub Date: 2017-05-23 DOI: 10.1039/C7CC02707A
Abstract
While investigating rhodium-catalyzed Negishi coupling, it was observed that the (PNP)Rh fragment readily inserted into zinc–carbon bonds to form isolable molecules with covalent rhodium–zinc bonds.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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