First hexanuclear copper(ii) pyrophosphate through hydrolysis of phosphodiester with a dicopper complex?

Chemical Communications Pub Date: 2009-08-06 DOI: 10.1039/B910094F

Abstract

Facile hydrolysis of a phosphodiester promoted by a dicopper bis(μ-hydroxo) complex containing a new biphenyl appended N-bidentate ligand led to the isolation of the first example of hexameric copper pyrophosphate through ‘in situ self assembly’.

Graphical abstract: First hexanuclear copper(ii) pyrophosphate through hydrolysis of phosphodiester with a dicopper complex
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