First aryl-substituted acyclic imino-N-heterocyclic carbene ligand precursor: synthesis, characterisation and coordination with silver(i) and copper(i)?

Dalton Transactions Pub Date: 2010-03-02 DOI: 10.1039/C002234A

Abstract

The first aryl-substituted imino-N-heterocyclic ligand precursor was prepared and structurally characterised, along with the corresponding silver(I) and copper(I) chloride complexes. An unusual T-shape coordination mode for the copper centre was observed.

Graphical abstract: First aryl-substituted acyclic imino-N-heterocyclic carbene ligand precursor: synthesis, characterisation and coordination with silver(i) and copper(i)
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