Functionalized chalcogenide hybrid inorganic/organic polymers (CHIPs) via inverse vulcanization of elemental sulfur and vinylanilines?
Polymer Chemistry Pub Date: 2018-03-27 DOI: 10.1039/C8PY00270C
Abstract
In this report, a new class of functional chalcogenide hybrid inorganic/organic polymers (CHIPs) bearing free aryl amine groups that are amenable to post-polymerization modifications were synthesized. These functional CHIPs were synthesized via the inverse vulcanization of elemental sulfur with 4-vinylaniline without the need for functional group protection of amines. This polymer is the first example of a polysulfide or CHIP material to carry a useful primary amine functional group which can be successfully post functionalized with acid chlorides and isocyanates to improve the mechanical properties.
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Journal Name：Polymer Chemistry
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CAS no.: 89640-58-4
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