fac-Re(CO)3-based neutral heteroleptic tetrahedrons?
Dalton Transactions Pub Date: 2019-04-11 DOI: 10.1039/C8DT05065A
Abstract
Four new flexible ditopic nitrogen donors possessing a xylene spacer and 2-phenylbenzimidazolyl or its derivatives as a coordinating unit and one rigid bis-chelating ligand consisting of two 2-hydroxyphenylbenzimidazolyl motifs and a central phenylene spacer were synthesized and further used with Re2(CO)10 for making a new family of neutral, heteroleptic tetrahedral-shaped supramolecular coordination complexes via a one-pot approach. The new ligands and the complexes were characterized using various analytical and spectroscopic methods. The molecular structures of the complexes were determined using single crystal X-ray diffraction analysis, which reveal that four rhenium cores are arranged in the vertices, and four ligands are at the edges of the tetrahedron.
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Journal Name：Dalton Transactions
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CAS no.: 89640-58-4
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