Dioxygen activation by a dinuclear nickel thiolate complex: structural characterization of the ligand oxidized product?

Chemical Communications Pub Date: 2003-01-14 DOI: 10.1039/B211395N

Abstract

A (μ-SR)2-nickel(II) dimer derived from a ligand with carboxamido nitrogen and thiolato sulfur donors reacts with O2 to afford an oxidized product in which phenyl groups of the ligand frames are oxidized to nickel-bound phenolates.

Graphical abstract: Dioxygen activation by a dinuclear nickel thiolate complex: structural characterization of the ligand oxidized product
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