Electrochemical oxidative decarboxylation and 1,2-aryl migration towards the synthesis of 1,2-diaryl ethers?
Chemical Science Pub Date: 2020-09-02 DOI: 10.1039/D0SC03708G
Abstract
Carboxylic acid compounds are important chemicals and are widely present in various natural products. They are not only nucleophiles, but also radical precursors. Classic transition-metal-catalyzed and photochemical decarboxylation have shown their excellent site selectivity in radical chemistry. However, electrochemical decarboxylation with a long history hasn't got enough attention in recent years. In this work, the electrochemical oxidative decarboxylation and 1,2-aryl migration of 3,3-diarylpropionic acids have been introduced to construct C–O bonds with alcohols. Remarkably, this transformation can proceed smoothly without metal catalysts and external oxidants.
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Journal Name：Chemical Science
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CAS no.: 89640-58-4
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