Cyclometalated (boroxinato)gold(iii) complexes from arrested transmetalation?

Chemical Communications Pub Date: 2015-09-08 DOI: 10.1039/C5CC05200A

Abstract

Organic boroxines are ubiquitous, but metallaboroxine analogues remain rare. A new class of (boroxinato)gold species are demonstrated here, as are observations of phosphorescence from boroxinato complexes. Four new compounds are crystallographically characterized.

Graphical abstract: Cyclometalated (boroxinato)gold(iii) complexes from arrested transmetalation
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