Effect of peptide orientation on electron transfer?

Physical Chemistry Chemical Physics Pub Date: 2010-07-14 DOI: 10.1039/C0CP00226G

Abstract

We have developed a methodology for the in situ derivatisation of histidine residues in self-assembled monolayers of peptides with redox-active groups, and have shown by electrochemical methods that the average dipole of peptide films on gold affects the heterogeneous electron transfer properties.

Graphical abstract: Effect of peptide orientation on electron transfer
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