Direct cross-coupling of benzyl alcohols to construct diarylmethanes via palladium catalysis?
Chemical Communications Pub Date: 2014-12-22 DOI: 10.1039/C4CC10084K
Abstract
A direct arylation to furnish diarylmethanes from benzyl alcohols was realized through Pd(PPh3)4-catalyzed Suzuki–Miyaura coupling via benzylic C–O activation in the absence of any additives. The arylation is compatible with various functional groups. This development provides an atom- and step-economic way to approach a diarylmethane scaffold under mild and environmentally benign conditions.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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