Conversion of a (sp3)C–F bond of alkyl fluorides to (sp3)C–X (X = Cl, C, H, O, S, Se, Te, N) bonds using organoaluminium reagents?

Chemical Communications Pub Date: 2006-11-23 DOI: 10.1039/B613641A

Abstract

A simple method for the conversion of (sp3)C–F bonds of alkyl fluorides to (sp3)C–X (X = Cl, C, H, O, S, Se, Te, N) bonds has been achieved by the use of a hexane solution of organoaluminum reagents having Al–X bonds.

Graphical abstract: Conversion of a (sp3)C–F bond of alkyl fluorides to (sp3)C–X (X = Cl, C, H, O, S, Se, Te, N) bonds using organoaluminium reagents
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