Direct oxidative coupling of thiols and benzylic ethers via C(sp3)–H activation and C–O cleavage to lead thioesters?
Organic & Biomolecular Chemistry Pub Date: 2014-11-14 DOI: 10.1039/C4OB02250E
Abstract
An unprecedented C–S formation method via direct oxidative C(sp3)–H bond functionalization and C–O cleavage of benzylic ethers was developed. Various thioesters including thioester structure containing drug intermediates could be achieved by this convenient, metal and base free method in satisfactory yields.
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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