Design and synthesis of a novel three-hindered quadrant bisphosphine ligand and its application in asymmetric hydrogenation?

Chemical Communications Pub Date: 2010-10-14 DOI: 10.1039/C0CC02620D

Abstract

A novel three hindered quadrant bisphosphine ligand has been synthesized. The ligand shows excellent enantioselectivities and reactivities for rhodium-catalyzed hydrogenations of various functionalized olefins.

Graphical abstract: Design and synthesis of a novel three-hindered quadrant bisphosphine ligand and its application in asymmetric hydrogenation
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