Cryptophanols, new versatile compounds for the synthesis of functionalized cryptophanes and polycryptophanes?

Chemical Communications Pub Date: 2001-12-14 DOI: 10.1039/B109301K

Abstract

After deprotection with a palladium catalyst, mono-allylated cryptophane-A (1, 2) and cryptophane-E (3) gave the new cryptophanols 4, 5 and 6, respectively, which are important key compounds for the preparation of mono-functionalized cryptophanes as well as for the design of large supramolecular hosts such as the bis-cryptophanes 7 and 8.

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