Copper(i)-catalyzed radical decarboxylative imidation of carboxylic acids with N-fluoroarylsulfonimides?
Chemical Communications Pub Date: 2016-08-23 DOI: 10.1039/C6CC03227C
Abstract
An efficient copper-catalyzed radical decarboxylative imidation reaction is presented. This strategy is carried out through the copper(I)-catalyzed decarboxylative C(sp3)–N and C(sp2)–N coupling of carboxylic acids with N-fluoroarylsulfonimides. The reaction shows good functional group tolerance and it provides a new approach for decarboxylative imidation. Preliminary mechanistic studies of this transformation suggest an involvement of N-centered radical species.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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