Copper(i)-catalyzed carbon–halogen bond-selective boryl substitution of alkyl halides bearing terminal alkene moieties?
Chemical Communications Pub Date: 2015-05-05 DOI: 10.1039/C5CC02760H
Abstract
The selective boryl substitution of alkyl halides bearing terminal C![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
C double bonds has been achieved using a copper(I)/tricyclohexylphosphine or copper(I)/o-diphenylphosphinophenol catalyst. This reaction represents a useful complementary approach to conventional procedures for the hydroboration of CC double bonds or the borylative cyclization of alkyl halides bearing terminal alkenes.
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Journal Name：Chemical Communications
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