Catalytic and stoichiometric flavanone oxidation mediated by nonheme oxoiron(iv) complexes as flavone synthase mimics: kinetic, mechanistic and computational studies?
Dalton Transactions Pub Date: 2018-09-13 DOI: 10.1039/C8DT03519A
Abstract
The present study describes the first example of the stoichiometric and catalytic oxidation of flavanone by synthetic nonheme oxoiron(IV) complexes and their precursor iron(II) complexes with m-CPBA as the terminal oxidant. These models, including detailed kinetic, mechanistic and computational studies, may serve as the biomimics of flavone synthase (FS) enzymes.
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Journal Name：Dalton Transactions
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CAS no.: 89640-58-4
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