Cascade covalent and coordination bond formation for Ti-based cage assembly: catalysis and coordination bifunctionality of TiCl4?
Dalton Transactions Pub Date: 2018-01-29 DOI: 10.1039/C7DT04367H
Abstract
The metallosupramolecular Ti-based M4L4 cage of [Ti4O2L4Cl8] (L = 4-acetamidobenzoic acid) is synthesized via the one-pot solvothermal reaction of 4-aminobenzoic acid, acetic acid and TiCl4. The Ti(IV) ion functions as a Lewis acid catalyst for acylation condensation, and then coordinates with the resultant 4-acetamidobenzoic acid to afford Ti-based cage formation in a cascade fashion.
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Journal Name：Dalton Transactions
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CAS no.: 89640-58-4
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