Copper-catalyzed borylamidation of vinyl arenes with isocyanates?
Chemical Communications Pub Date: 2020-05-27 DOI: 10.1039/C9CC09902F
Abstract
A copper-catalyzed borylative amidation of vinyl arenes with isocyanates and bis(pinacolato)diboron has been developed. This new protocol, which can be performed on a gram-scale, utilizes isocyanates as simple precursors to provide access to a range of boryl alkyl amides. The products contain valuable amide and boronate, which are amenable for further elaboration, and have versatile synthetic utilities.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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