Copper-catalyzed arylstannylation of arynes in a sequence?
Chemical Communications Pub Date: 2019-05-10 DOI: 10.1039/C9CC02738F
Abstract
Copper-catalyzed arylstannylation of arynes has been developed. This transformation enables variously substituted ortho-stannylbiaryls and teraryls to be constructed straightforwardly. An electron-deficient tin center is the key, and thus the single or dual insertion of arynes into arylstannanes is precisely controllable by simply changing the equivalence of aryne precursors.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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