CO, CO2 and CS2 activation by divalent ytterbium hydrido complexes?
Chemical Communications Pub Date: 2021-12-21 DOI: 10.1039/D1CC06449E
Abstract
Treatment of a divalent ytterbium hydride complex [(TpAd,iPr)Yb(H)(THF)] (TpAd,iPr = hydrotris(3-adamantyl-5-isopropyl-pyrazolyl)borate) (1) with CO, CO2 and CS2 resulted in the formation of a divalent ytterbium ethenediolate complex [(TpAd,iPr)Yb]2(cis-OCH![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
CHO) (2), a formate complex [(TpAd,iPr)Yb(κ2-O2CH)(THF)] (3), and a trivalent ytterbium ethenetetrathiolate complex [(TpAd,iPr)YbIII]2(C2S4) (4), respectively. DFT calculations were carried out to elucidate the reaction profiles of complexes 3 and 4.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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