Post-transition metal oxoanionic compounds
Post-transition metal oxoanionic compounds are a class of inorganic compounds featuring a post-transition metal center bound to one or more oxygen atoms, typically forming an anion. These compounds play significant roles in various fields such as catalysis and materials science due to their unique electronic structures and reactivity.
The term "post-transition" refers to elements beyond the 3d transition metals, including lanthanides and actinides, which possess different electronic configurations and properties compared to traditional transition metals. The oxoanions can exhibit diverse coordination geometries, ranging from linear to more complex polyhedral structures, depending on the post-transition metal's valence electron count.
These compounds are often studied for their potential applications in energy storage, environmental remediation, and pharmaceuticals. For instance, certain lanthanide oxoanions have shown promise as catalysts in organic synthesis reactions, while actinide-based materials can be used in radioactive waste management processes. The stability and reactivity of these species can be tuned by altering the coordination environment around the post-transition metal center, making them versatile candidates for advanced material design and development.
- Post-transition metal sulfates
- Post-transition metal perchlorates
- Post-transition metal silicates
- Post-transition metal nitrates
- Post-transition metal chromates
- Post-transition metal selenites
- Post-transition metal sulfites
- Post-transition metal aluminates
- Post-transition metal tungstates
- Post-transition metal hydroxides
- Post-transition metal phosphates
- Post-transition metal molybdates
- Post-transition metal selenates
- Post-transition metal phosphites
- Post-transition metal chlorates
- Post-transition metal borates
- Post-transition metal bromates
Related Literature
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J. Xu,T. J. Carrocci,A. A. Hoskins Chem. Commun., 2016,52, 549-552
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Long Deng,Qian Zou,Biao Liu,Wenhui Ye,Chengfei Zhuo,Li Chen,Ze-Yuan Deng,Ya-Wei Fan,Jing Li Food Funct., 2018,9, 4234-4245
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Matthew J. Gaunt,Jinquan Yu,Jonathan B. Spencer Chem. Commun., 2001, 1844-1845
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Albertus D. Handoko,Khoong Hong Khoo,Teck Leong Tan,Hongmei Jin,Zhi Wei Seh J. Mater. Chem. A, 2018,6, 21885-21890
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Xiaoming Liu,Zachary D. Hood,Wangda Li,Donovan N. Leonard,Arumugam Manthiram,Miaofang Chi J. Mater. Chem. A, 2021,9, 2111-2119
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