Phenylazides
Phenylazides are a class of organic compounds featuring a phenyl group attached to an azide functional group (-N3). These compounds are typically prepared by reacting phenols with sodium nitrite in the presence of an acid catalyst. Phenylazides are known for their instability, which often results in the formation of toxic gases such as nitrogen trichloride and nitrogen dioxide upon exposure to heat or light. Due to their reactivity, they are primarily used in synthetic organic chemistry as precursors for various amino compounds. Additionally, phenylazides can be employed in the preparation of dyes, pharmaceuticals, and other industrial applications where reactive azide functionality is required. The high reactivity of phenylazides makes them valuable tools in academic and commercial research settings.
| Structure | Chemical Name | CAS | MF |
|---|---|---|---|
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1-azido-2-iodobenzene | 54467-95-7 | C6H4IN3 |
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Propanoic acid,3-[(4-azidophenyl)dithio]-, 2,5-dioxo-1-pyrrolidinyl ester | 74676-98-5 | C13H12N4O4S2 |
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Disulfide,bis(4-azidophenyl) | 37434-06-3 | C12H8N6S2 |
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2,5-Cyclohexadiene-1,4-dione,2,3,5,6-tetraazido- | 22826-61-5 | C6N12O2 |
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2-azido-1,3-dimethylbenzene | 26334-20-3 | C8H9N3 |
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Benzene,1-azido-2,4,5-trimethyl- | 147647-81-2 | C9H11N3 |
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1-azido-2,4-dichlorobenzene | 1965-25-9 | C6H3Cl2N3 |
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2-azido-1,3-difluorobenzene | 102284-85-5 | C6H3F2N3 |
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1-azido-2-(bromomethyl)benzene | 31553-17-0 | C7H6BrN3 |
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3-Azido-2-methylbenzonitrile | 188867-90-5 | C8H6N4 |
Related Literature
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Andreas Nenning,Manuel Holzmann,Jürgen Fleig,Alexander K. Opitz Mater. Adv., 2021,2, 5422-5431
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Long Deng,Qian Zou,Biao Liu,Wenhui Ye,Chengfei Zhuo,Li Chen,Ze-Yuan Deng,Ya-Wei Fan,Jing Li Food Funct., 2018,9, 4234-4245
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Gloria Belén Ramírez-Rodríguez,José Manuel Delgado-López,Jaime Gómez-Morales CrystEngComm, 2013,15, 2206-2212
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