Organic phosphines and derivatives
Organic phosphines and their derivatives are a class of compounds containing at least one phosphorus atom bonded to organic groups, typically aliphatic or aromatic hydrocarbons. These compounds play crucial roles in various applications within the chemical industry due to their unique reactivity and electronic properties.
Phosphine compounds can be synthesized through the reduction of phosphorus halides or metal derivatives. They are widely used as ligands in homogeneous catalysis, particularly in the hydrogenation of olefins and aromatics, where they act as electron donors to stabilize transition metal complexes. Additionally, organophosphines serve as excellent reductants and nucleophiles in organic synthesis, facilitating reactions such as coupling reactions and hydroamination.
Derivatives of phosphines include phosphine oxides, phosphine sulfides, and other functionalized analogs that offer enhanced stability or additional functionalities. These derivatives maintain the versatility of phosphines while expanding their application scope to areas like pharmaceuticals, pesticides, and fine chemicals. Their ability to act as bifunctional reagents makes them indispensable in the synthesis of complex organic structures, contributing significantly to both academic research and industrial processes.
| Structure | Chemical Name | CAS | MF |
|---|---|---|---|
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Dichloro(tricyclohexylphosphine)(tricyclohexylphosphoranylidene)methylruthenium tetrafluoroborate | 1020085-61-3 | C37H67BCl2F4P2Ru |
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di-n-butylmethylphosphine | 33374-48-0 | C9H21P |
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(S)-[Rh COD TCFP]BF4 | 705945-68-2 | C22H44BF4P2Rh |
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Phosphine, 1-butynyldiethyl- | 194038-21-6 | C8H15P |
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ditert-butyl(cyclobutylmethyl)phosphane | 111857-32-0 | C13H27P |
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Tert-butyl-cyclohexyl-methylphosphane | 74685-81-7 | C11H23P |
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Di-tert-butylphosphinoferrocene | 223655-16-1 | C18H27FeP |
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Bis(dicyclohexylphosphino)methane | 137349-65-6 | C25H46P2 |
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Nickel,dibromobis(tributylphosphine)- | 15242-92-9 | C24H54Br2NiP2 |
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Tris(hydroxypropyl)phosphine | 4706-17-6 | C9H21O3P |
Related Literature
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Sandip Gangadhar Balwe,Yeon Tae Jeong Org. Biomol. Chem., 2018,16, 1287-1296
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Huifang Yang,Haoran Guo,Peidong Fan,Xinpan Li,Wenlu Ren,Rui Song Nanoscale, 2020,12, 7024-7034
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Jieun Kim,Han-Saem Park,Tae-Hee Kim,Sung Yeol Kim,Hyun-Kon Song Phys. Chem. Chem. Phys., 2014,16, 5295-5300
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Jing Chen,Yu Shao,Danzhen Li J. Mater. Chem. A, 2017,5, 937-941
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Eunhak Lim,Jiyoung Heo,Seong Keun Kim Nanoscale, 2019,11, 11369-11378
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