Organic oxoazanium compounds
Oxoazanium compounds are a class of organic chemical species characterized by the presence of an oxoazanium ion, which features an oxygen atom bonded to a positively charged nitrogen. These compounds can be synthesized through various reactions, such as protonation of aziridines or other nitrogen-containing heterocycles in the presence of strong acids. Oxoazanium ions are known for their high reactivity and ability to undergo rapid rearrangements, making them valuable intermediates in organic synthesis. They play crucial roles in facilitating a wide range of chemical transformations, including Michael addition reactions, [3+2] cycloadditions, and ring-opening reactions. Due to their unique structural features and reactivity, oxoazanium compounds are extensively utilized in the preparation of heterocycles, pharmaceuticals, and functional materials.
| Structure | Chemical Name | CAS | MF |
|---|---|---|---|
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Pyrazine,2,3,5,6-tetramethyl-, 1,4-dioxide | 22978-84-3 | C8H12N2O2 |
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Pyrazine, 2,5-dimethyl-, 1,4-dioxide | 6890-38-6 | C6H8N2O2 |
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Pyrazine 1,4-Dioxide-d4 | 933803-86-2 | C4H4N2O2 |
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Pyrazine, 2-methyl-,1,4-dioxide | 32046-26-7 | C5H6N2O2 |
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Pyrazine, 2,6-dimethyl-, 1,4-dioxide | 74428-43-6 | C6H8N2O2 |
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Pyrazine, 2,5-bis(1-methylethyl)-, 1,4-dioxide | 65257-61-6 | C10H16N2O2 |
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2-Pyrazinol,2,3-dihydro-3,3-dimethyl-, 1,4-dioxide | 88571-67-9 | C6H10N2O3 |
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Pyrazine,2,3-dihydro-2,2,3,5,6-pentamethyl-, 1,4-dioxide | 152860-44-1 | C9H16N2O2 |
Related Literature
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Abdelaziz Houmam,Emad M. Hamed Chem. Commun., 2012,48, 11328-11330
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Peiyuan Zeng,Xiaoxiao Wang,Ming Ye,Qiuyang Ma,Jianwen Li,Wanwan Wang,Baoyou Geng,Zhen Fang RSC Adv., 2016,6, 23074-23084
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