Lanthanide fluorides
Lanthanide fluorides are inorganic compounds consisting of lanthanide elements combined with fluoride ions (F?). These materials exhibit a range of interesting properties due to the unique electronic configurations and strong ionic bonding between the lanthanide cations and fluoride anions. Lanthanum fluoride, for instance, is known for its high refractive index and photoluminescent properties, making it suitable for optical applications such as laser crystals, phosphors, and glass additives.
Other lanthanide fluorides, like europium(III) fluoride (EuF3), are highly luminescent and find application in fluorescent lamps and display technologies. Dysprosium trifluoride (DyF3) is valued for its strong magnetic properties at elevated temperatures, which makes it useful in magnetic storage devices and sensors.
These compounds can be synthesized via various methods, including precipitation, co-precipitation, and fluorination reactions under controlled conditions to ensure purity and crystallinity. The resulting materials are often characterized by techniques such as X-ray diffraction (XRD), thermogravimetric analysis (TGA), and spectroscopy to confirm their structure and composition.
Overall, lanthanide fluorides play a significant role in advanced technologies and continue to be of great interest for both academic research and industrial applications.
| Structure | Chemical Name | CAS | MF |
|---|---|---|---|
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YTTERBIUM FLUORIDE OXIDE | 15587-02-7 | FHOYb |
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Praseodymium fluoride | 13709-46-1 | F3Pr |
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Dysprosium fluoride | 13569-80-7 | DyF3 |
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Ytterbium Fluoride | 13760-80-0 | F3Yb |
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lutetium trifluoride | 13760-81-1 | F3Lu |
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erbium trifluoride | 13760-83-3 | ErF3 |
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Cerium fluoride (CeF4) | 10060-10-3 | CeF4 |
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DIDYMIUM FLUORIDE | 58516-57-7 | F6NdPr |
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thulium(iii) fluoride | 13760-79-7 | F3Tm |
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Terbium fluoride (TbF4)(9CI) | 36781-15-4 | F4Tb |
Related Literature
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Norihito Fukui,Keisuke Fujimoto,Hideki Yorimitsu,Atsuhiro Osuka Dalton Trans., 2017,46, 13322-13341
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Alena Koukalová,?árka Pokorná,Aimee L. Boyle,Nestor Lopez Mora,Alexander Kros,Martin Hof,Radek ?achl Nanoscale, 2018,10, 19064-19073
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J. Xu,T. J. Carrocci,A. A. Hoskins Chem. Commun., 2016,52, 549-552
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Hongxia Li,Aikifa Raza,Qiaoyu Ge,Jin-You Lu,TieJun Zhang Soft Matter, 2020,16, 6841-6849
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Marcin Czapla,Jack Simons Phys. Chem. Chem. Phys., 2018,20, 21739-21745
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