Enoate esters
Enoate esters, also known as beta-carboxylic acid esters or enoyl esters, are a class of organic compounds characterized by the presence of an ester group (-COO-) attached to a beta carbon of a hydrocarbon chain. These molecules often exhibit unique reactivity due to the proximity of the carboxylate group and the double bond (C=C) on adjacent carbons.
Enoate esters find applications in various fields including pharmaceuticals, agrochemicals, and materials science. Their chemical structure allows for diverse modifications, which can lead to compounds with specific functional properties. For instance, in drug design, enoate esters can be used as prodrugs or as intermediates in the synthesis of more complex molecules.
Structurally, these esters consist of a hydrocarbon chain containing a conjugated double bond and an ester group attached at the beta position relative to the double bond. Their stability and reactivity make them valuable in organic synthesis, where they can participate in various reactions such as esterifications, acylations, and nucleophilic substitutions.
Due to their specific functional groups and structure, enoate esters play crucial roles in developing new materials with tailored properties for industrial applications.
| Structure | Chemical Name | CAS | MF |
|---|---|---|---|
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Curvulide B1 | 1058150-15-4 | C10H12O4 |
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Curvulide B1; 4-Epimer | 1058150-16-5 | C10H12O4 |
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Cattienoid A | 1616472-04-8 | C24H32O4 |
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Cattienoid A; Deoxy | 2365389-97-3 | C24H32O3 |
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Cattienoid B | 1616472-05-9 | C22H28O3 |
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Cattienoid B; 15β-Hydroxy | 2365389-98-4 | C22H28O4 |
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2-Oxepincarboxylic acid, methyl ester (9CI); | 67490-10-2 | C8H8O3 |
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methyl (1R,5R,6S)-5-hydroxy-7-oxabicyclo[4.1.0]hept-2-ene-3-carboxylate | 90866-43-6 | C8H10O4 |
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2-Propenoic acid, 2-methyl-, 2-methyl-2-butenyl ester, (E)- | 88142-95-4 | C9H14O2 |
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Acetic acid, 2-cyclohexen-1-ylidene-, methyl ester, (2Z)- | 51326-25-1 | C9H12O2 |
Related Literature
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Li-Hua Gan,Rui Wu,Jian-Lei Tian,Patrick W. Fowler Phys. Chem. Chem. Phys., 2017,19, 419-425
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Alvin Tanudjaja,Shinsuke Inagi,Fusao Kitamura,Toshikazu Takata,Ikuyoshi Tomita Dalton Trans., 2021,50, 3037-3043
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Kanjun Sun,Fengting Hua,Shuzhen Cui,Yanrong Zhu,Hui Peng,Guofu Ma RSC Adv., 2021,11, 37631-37642
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Piotr Szcze?niak,Sebastian Stecko RSC Adv., 2015,5, 30882-30888
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Yaqing Liu,Jiangtao Ren,Jing Li,Jiyang Liu,Erkang Wang Chem. Commun., 2012,48, 802-804
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