Biphenylcarbonitriles
Biphenylcarbonitriles are a class of organic compounds characterized by the presence of two phenyl rings connected via a nitrile group (-CN). These materials exhibit unique chemical and physical properties due to their aromatic structure, making them valuable in various applications. Structurally, these compounds can be represented as C6H4-CN-C6H4, where the nitrile group is located between two benzene rings.
Biphenylcarbonitriles are widely used in the synthesis of other complex organic molecules and materials due to their reactivity with nucleophiles. They serve as key intermediates in the production of polymers, pharmaceuticals, and dyes. Additionally, these compounds have potential applications in electronics and photonic devices owing to their excellent electrical conductivity and optical properties.
Their preparation often involves reactions such as Friedel-Crafts acylation followed by nitrilation or direct synthesis from benzene derivatives under appropriate conditions. The stability of biphenylcarbonitriles makes them suitable for various synthetic processes, though they require careful handling due to their reactivity.
| Structure | Chemical Name | CAS | MF |
|---|---|---|---|
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3,3'-Dicyanobiphenyl | 36852-02-5 | C14H8N2 |
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4-Phenylbenzonitrile | 2920-38-9 | C13H9N |
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4-(4-Aminophenyl)benzonitrile | 4854-84-6 | C13H10N2 |
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4-(4-Chlorophenyl)benzonitrile | 57774-36-4 | C13H8ClN |
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4-(4-Methoxyphenyl)benzonitrile | 58743-77-4 | C14H11NO |
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(S)-4'-(2-Methylbutyl)-1,1'-biphenyl-4-carbonitrile | 63799-11-1 | C18H19N |
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N-(2'-Cyano1,1'-biphenyl-4-yl)methyl-L-valine Methyl Ester Hydrochloride | 482577-59-3 | C20H23ClN2O2 |
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Des2’-(1H-tetrazol-5-yl) 2-Cyanolosartan | 114772-55-3 | C22H22ClN3O |
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4-4-(Trifluoromethoxy)phenylbenzonitrile | 157788-40-4 | C14H8F3NO |
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4-(4-Hexoxyphenyl)benzonitrile | 41424-11-7 | C19H21NO |
Related Literature
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Stephen P. Fletcher,Richard B. C. Jagt,Ben L. Feringa Chem. Commun., 2007, 2578-2580
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Yang Chen,Di Zhou,Zheyi Meng,Jin Zhai Chem. Commun., 2016,52, 10020-10023
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Karl Crowley,Eimer O'Malley,Aoife Morrin,Malcolm R. Smyth,Anthony J. Killard Analyst, 2008,133, 391-399
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Eunhak Lim,Jiyoung Heo,Seong Keun Kim Nanoscale, 2019,11, 11369-11378
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Huifang Yang,Haoran Guo,Peidong Fan,Xinpan Li,Wenlu Ren,Rui Song Nanoscale, 2020,12, 7024-7034
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