Benzidines
Benzidines are a class of organic compounds that contain an aromatic ring system with a specific functional group structure characterized by two nitrogen atoms and one carbon atom forming a secondary amine. These compounds are widely recognized for their potential use in various applications such as dyes, pharmaceuticals, and agricultural chemicals due to their structural diversity and reactivity.
Structurally, benzidines feature an aromatic nucleus typically linked via the nitrogen atoms, making them versatile building blocks in organic synthesis. They can undergo numerous chemical reactions including electrophilic substitution at positions 2, 3, or 6 of the aromatic ring. This functionality makes benzidines valuable intermediates for synthesizing a wide array of compounds with specific functional groups.
In the dye industry, these molecules are used to produce vibrant and colorfast dyes that adhere well to textiles. In pharmaceutical applications, they can serve as starting materials for developing drugs due to their ability to form stable complexes or undergo ring-opening reactions. Additionally, in agriculture, benzidines might be employed in herbicides or fungicides where their chemical properties enable effective weed control or pathogen inhibition.
Overall, the broad applicability of benzidines across multiple sectors highlights their importance as a fundamental component in synthetic organic chemistry and material science.
| Structure | Chemical Name | CAS | MF |
|---|---|---|---|
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2,2'-Dimethyl-1,1'-biphenyl-4,4'-diamine | 84-67-3 | C14H16N2 |
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3,3'-Dichlorobiphenyl-4,4'-diamine | 91-94-1 | C12H10Cl2N2 |
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[1,1'-Biphenyl]-3,4,4'-triamine | 17828-45-4 | C12H13N3 |
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3,3'-(biphenyl-4,4'-diyldidiazene-2,1-diyl)bis(4-aminonaphthalene-1-sulfonic acid) | 14684-01-6 | C32H24N6O6S2 |
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| 70894-13-2 | C12H12N2O2 |
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Biphenyl-2,4,4'-triamine | 2835-69-0 | C12H13N3 |
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4,4'-Diamino-2,2’-difluorobiphenyl | 316-64-3 | C12H10F2N2 |
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Congo red | 573-58-0 | C32H22N6Na2O6S2 |
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2,2'-Bis(trifluoromethyl)benzidine | 341-58-2 | C14H10F6N2 |
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Chromocitronine | 6232-49-1 | C26H14N4Na4O12S2 |
Related Literature
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Bin Han,Yasuo Shimizu,Gabriele Seguini,Celia Castro,Gérard Ben Assayag,Koji Inoue,Yasuyoshi Nagai,Sylvie Schamm-Chardon,Michele Perego RSC Adv., 2016,6, 3617-3622
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David White,Sean R. Stowell Biomater. Sci., 2017,5, 463-474
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Andreas Nenning,Manuel Holzmann,Jürgen Fleig,Alexander K. Opitz Mater. Adv., 2021,2, 5422-5431
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Ana G. Neo,Ana Bornadiego,Jesús Díaz,Stefano Marcaccini,Carlos F. Marcos Org. Biomol. Chem., 2013,11, 6546-6555
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