Alpha-haloketones
Alpha-haloketones are a class of organic compounds characterized by the presence of a halogen atom (such as chlorine, bromine, or iodine) directly attached to the alpha-carbon of a ketone group. These functional groups exhibit diverse reactivity and can be found in natural products and synthetic intermediates.
The structure of an alpha-haloketone typically consists of a carbonyl group (C=O) with a halogen atom attached to the carbon adjacent to the carbonyl, which is often referred to as the alpha-carbon. The presence of the halogen can influence the reactivity and selectivity in various chemical reactions.
Due to their versatile properties, alpha-haloketones are widely used in organic synthesis for the preparation of a wide range of compounds. They serve as valuable precursors in the construction of more complex molecules through processes such as nucleophilic substitution or other functional group transformations. Additionally, some alpha-haloketones have found applications in pharmaceuticals and agrochemicals due to their unique chemical properties.
| Structure | Chemical Name | CAS | MF |
|---|---|---|---|
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2-Heptanone, 1,3,3-tribromo- | 54899-96-6 | C7H11Br3O |
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Perforaton | 132342-61-1 | C15H22Br2O |
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1,1,3-Tribromo-2-heptanone | 54899-95-5 | C7H11Br3O |
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1,3-Dibrom-2-heptanon | 1577-30-6 | C7H12Br2O |
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3,3-dibromo-1-iodoheptan-2-one | 54899-97-7 | C7H11Br2IO |
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1,1,3,3-tetrabromoheptan-2-one | 54899-94-4 | C7H10Br4O |
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Perforaton | 125136-26-7 | C15H22Br2O |
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1,1,3,3-Tetrabromoacetone | 22612-89-1 | C3H2Br4O |
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Perforaton | 57566-98-0 | C15H22Br2O |
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2-Propanone, 1,1-dibromo-3-iodo- | 59227-99-5 | C3H3Br2IO |
Related Literature
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Hongxia Li,Aikifa Raza,Qiaoyu Ge,Jin-You Lu,TieJun Zhang Soft Matter, 2020,16, 6841-6849
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Joseph W. Bennett,Diamond T. Jones,Blake G. Hudson,Joshua Melendez-Rivera,Robert J. Hamers,Sara E. Mason Environ. Sci.: Nano, 2020,7, 1642-1651
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Brindha J.,Balamurali M. M.,Kaushik Chanda RSC Adv., 2019,9, 34720-34734
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Byungho Lim,Jaewon Jin,Jin Yoo,Seung Yong Han,Kyeongyeol Kim,Sungah Kang,Nojin Park,Sang Moon Lee,Hae Jin Kim,Seung Uk Son Chem. Commun., 2014,50, 7723-7726
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Norihito Fukui,Keisuke Fujimoto,Hideki Yorimitsu,Atsuhiro Osuka Dalton Trans., 2017,46, 13322-13341
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