Alpha-branched alpha,beta-unsaturated ketones
Alpha-branched alpha,beta-unsaturated ketones are a class of organic compounds characterized by the presence of an unsaturated carbonyl group (C=C-C=O) with an alkyl or alkenyl group attached to the carbon atom adjacent to the carbonyl group. These molecules exhibit versatile reactivity and are widely used in various applications, including the synthesis of complex organic structures, pharmaceuticals, agrochemicals, and materials science. The branching pattern can significantly influence their physical properties and chemical behavior, making them valuable intermediates or building blocks for diverse reactions such as Michael addition, Diels-Alder reactions, and intramolecular cyclization processes. Due to their high reactivity and functional diversity, these compounds are essential in organic synthesis and offer a broad spectrum of potential applications across different industries.
| Structure | Chemical Name | CAS | MF |
|---|---|---|---|
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3-Buten-2-one, 1,1,3,4-tetrabromo-, (Z)- | 56020-83-8 | C4H2Br4O |
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1-Penten-3-one, 5-(3-furanyl)-2-methyl- | 80445-58-5 | C10H12O2 |
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Bryophollenone | 124877-90-3 | C23H34O5 |
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(2S,3R,4S,4'R)-(+)-botryodiplodinenone | 948039-52-9 | C14H22O4 |
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(2R,3R,4S,4'S)-(-)-2-epi-botryodiplodinenone | 948039-54-1 | C14H22O4 |
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1,7-octadien-3-one, 2-methyl-6-methylene- | 41702-60-7 | C10H14O |
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1-Octen-3-one,1,1,2,4-tetrabromo- | 64822-80-6 | C8H10Br4O |
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1-Octen-3-one,1,1,2-tribromo- | 64785-96-2 | C8H11Br3O |
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2-Cyclopenten-1-one, 3-[(1E,3E,5E,7E,9E)-2,10-dimethyl-11-oxo-1,3,5,7,9-dodecapentaen-1-yl]-2,5-dimethyl-, (5R)- | 197631-44-0 | C21H26O2 |
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(4Z,6S,7R)-7-bromo-4,6,8-trichloro-2,6-dimethylocta-1,4-dien-3-one | 89353-92-4 | C10H12BrCl3O |
Related Literature
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Xiaofeng Lin RSC Adv., 2016,6, 9002-9006
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Dhamodaran Manikandan,S. Amirthapandian,I. S. Zhidkov,A. I. Kukharenko,S. O. Cholakh,Ramaswamy Murugan Phys. Chem. Chem. Phys., 2018,20, 6500-6514
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Yu-Nong Li,Liang-Nian He,Xian-Dong Lang,Xiao-Fang Liu,Shuai Zhang RSC Adv., 2014,4, 49995-50002
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