Alkali metal nitrides
Alkali metal nitrides are a class of chemical compounds that consist of alkali metals in the first group of the periodic table combined with nitrogen. These materials are highly reactive and typically form upon the reaction of nitrogen gas (N?) with an alkali metal at elevated temperatures or under specific conditions. Sodium nitride (Na?N), lithium nitride (Li?N), and potassium nitride (K?N) are notable examples within this category.
Sodium nitride, for instance, has a cubic structure and is widely used in the production of ammonia via the Haber process, where it reacts with hydrogen gas to form ammonia. Lithium nitride can be produced by reacting lithium metal with nitrogen and exhibits properties useful in certain electronic applications due to its high thermal stability. Potassium nitride also crystallizes in a cubic structure but is less studied compared to sodium and lithium nitrides.
These compounds are of significant interest in various scientific fields, including materials science, catalysis, and chemical engineering, owing to their unique reactivity and potential applications. However, they must be handled with great caution due to their strong reactivity and flammability.
| Structure | Chemical Name | CAS | MF |
|---|---|---|---|
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Lithamide | 7782-89-0 | H2LiN |
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Cesium azide | 22750-57-8 | CsN3 |
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Lithium Azide (~20% in Water) | 19597-69-4 | LiN3 |
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SodiuM Azide-15N3 | 1015486-10-8 | N3Na |
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Zincate(2-),tetrakis(cyano-kC)-,potassium (1:2), (T-4)- | 14244-62-3 | C4K2N4Zn |
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sodium azanide | 7782-92-5 | H2NNa |
Related Literature
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Stephen P. Fletcher,Richard B. C. Jagt,Ben L. Feringa Chem. Commun., 2007, 2578-2580
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Chongyang Zhu,Xiaojia Bian,Xin Jia,Ning Tang,Yongqiang Cheng Food Funct., 2020,11, 10635-10644
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Hyejin Moon,Aaron R. Wheeler,Robin L. Garrell,Chang-Jin “CJ” Kim Lab Chip, 2006,6, 1213-1219
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Piotr Szcze?niak,Sebastian Stecko RSC Adv., 2015,5, 30882-30888
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