Cas no 983-80-2 ((Z)-1,2-Bis(diphenylphosphino)ethene)
(Z)-1,2-Bis(diphenylphosphino)ethene Chemical and Physical Properties
Names and Identifiers
-
- (Z)-1,2-Bis(diphenylphosphino)ethene
- cis-1,2-Bis(diphenylphosphino)ethylene
- [(Z)-2-diphenylphosphanylethenyl]-diphenylphosphane
- cis-1,2-Bis(diphenylphosphino)ethene
- cis-Vinylenebis(diphenylphosphine)
- cis-1,2-Bis(diphenylphosphine)ethylene
- cis-Bis(diphenylphosphino)ethylene
- cis-Vinylenebis[diphenylphosphine]
- Phosphine, vinylenebis(diphenyl-, (E)-
- NSC-132587
- NCKJIJSEWKIXAT-DQRAZIAOSA-N
- Phosphine, 1,2-ethenediylbis[diphenyl-, (E)-
- [(Z)-2-diphenylphosphanylvinyl]-diphenyl-phosphane
- Phosphine, trans-
- trans-Vinylenebis[diphenylphosphine]
- CS-W009728
- NSC132588
- DTXSID601283879
- A845853
- NSC132587
- 983-80-2
- cis-1,2-Bis(diphenylphosphino)ethylene, 97%
- CHEMBL2114057
- NSC-132588
- [(1Z)-2-(diphenylphosphanyl)ethenyl]diphenylphosphane
- [(Z)-2-(Diphenylphosphino)ethenyl](diphenyl)phosphine #
- trans-Vinylenebis(diphenylphosphine)
- Phosphine, vinylenebis(diphenyl-, trans-
- Phosphine,2-ethenediylbis[diphenyl-, (E)-
- EINECS 213-569-7
- SCHEMBL338474
- 1,2-bis(diphenylphosphino)ethylene
- AKOS002263216
- trans-1,2-Bis(diphenylphosphinyl)ethylene
- AS-62969
- Phosphine, (E)-
- NSC 132588
- A12963
- DB-243274
-
- MDL: MFCD00003046
- Inchi: 1S/C26H22P2/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26/h1-22H/b22-21-
- InChI Key: NCKJIJSEWKIXAT-DQRAZIAOSA-N
- SMILES: P(/C=C\P(C1C=CC=CC=1)C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1
- BRN: 757792
Computed Properties
- Exact Mass: 396.12000
- Monoisotopic Mass: 396.12
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 0
- Heavy Atom Count: 28
- Rotatable Bond Count: 6
- Complexity: 371
- Covalently-Bonded Unit Count: 1
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 1
- Undefined Bond Stereocenter Count: 0
- Surface Charge: 0
- XLogP3: 5.9
- Topological Polar Surface Area: 0
Experimental Properties
- Color/Form: Not determined
- Melting Point: 122-124?°C (lit.)
- Boiling Point: 546.8 °C at 760 mmHg
- Flash Point: 302.7 °C
- Water Partition Coefficient: Insoluble in water.
- PSA: 27.18000
- LogP: 5.72340
- Solubility: Not determined
- Sensitiveness: Air Sensitive
(Z)-1,2-Bis(diphenylphosphino)ethene Security Information
-
Symbol:
- Signal Word:Warning
- Hazard Statement: H315-H319-H335
- Warning Statement: P261-P305 + P351 + P338
- Hazardous Material transportation number:NONH for all modes of transport
- WGK Germany:3
- Hazard Category Code: 36/37/38
- Safety Instruction: 26-37/39
-
Hazardous Material Identification:
- Risk Phrases:R36/37/38
(Z)-1,2-Bis(diphenylphosphino)ethene Customs Data
- HS CODE:2902909090
- Customs Data:
China Customs Code:
2902909090Overview:
2902909090. Other aromatic hydrocarbons. VAT:17.0%. Tax refund rate:9.0%. Regulatory conditions:nothing. MFN tariff:2.0%. general tariff:30.0%
Declaration elements:
Product Name, component content
Summary:
2902909090 other aromatic hydrocarbons.Supervision conditions:None.VAT:17.0%.Tax rebate rate:9.0%.MFN tariff:2.0%.General tariff:30.0%
(Z)-1,2-Bis(diphenylphosphino)ethene Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| SHANG HAI A LA DING SHENG HUA KE JI GU FEN Co., Ltd. | C139508-5g |
(Z)-1,2-Bis(diphenylphosphino)ethene |
983-80-2 | ≥97% | 5g |
¥2146.90 | 2023-09-03 | |
| SHANG HAI A LA DING SHENG HUA KE JI GU FEN Co., Ltd. | C139508-250mg |
(Z)-1,2-Bis(diphenylphosphino)ethene |
983-80-2 | ≥97% | 250mg |
¥201.90 | 2023-09-03 | |
| SHANG HAI A LA DING SHENG HUA KE JI GU FEN Co., Ltd. | C139508-1g |
(Z)-1,2-Bis(diphenylphosphino)ethene |
983-80-2 | ≥97% | 1g |
¥512.90 | 2023-09-03 | |
| A FA AI SHA , SAI MO FEI SHI ER KE JI QI XIA GONG SI | A16859-1g |
cis-1,2-Bis(diphenylphosphino)ethylene, 97% |
983-80-2 | 97% | 1g |
¥976.00 | 2023-03-14 | |
| A FA AI SHA , SAI MO FEI SHI ER KE JI QI XIA GONG SI | A16859-5g |
cis-1,2-Bis(diphenylphosphino)ethylene, 97% |
983-80-2 | 97% | 5g |
¥3332.00 | 2023-03-14 | |
| Alichem | A019112408-5g |
(Z)-1,2-Bis(diphenylphosphino)ethene |
983-80-2 | 95% | 5g |
$194.93 | 2023-08-31 | |
| SHANG HAI YI EN HUA XUE JI SHU Co., Ltd. | R025938-1g |
(Z)-1,2-Bis(diphenylphosphino)ethene |
983-80-2 | 97% | 1g |
¥531 | 2024-07-19 | |
| SHANG HAI YI EN HUA XUE JI SHU Co., Ltd. | R025938-250mg |
(Z)-1,2-Bis(diphenylphosphino)ethene |
983-80-2 | 97% | 250mg |
¥133 | 2024-07-19 | |
| SHANG HAI YI EN HUA XUE JI SHU Co., Ltd. | R025938-50mg |
(Z)-1,2-Bis(diphenylphosphino)ethene |
983-80-2 | 97% | 50mg |
¥53 | 2024-07-19 | |
| SHANG HAI MAI KE LIN SHENG HUA Technology Co., Ltd. | B863509-1g |
cis-1,2-Bis(diphenylphosphino)ethylene |
983-80-2 | ≥97% | 1g |
¥832.00 | 2022-09-02 |
(Z)-1,2-Bis(diphenylphosphino)ethene Suppliers
(Z)-1,2-Bis(diphenylphosphino)ethene Related Literature
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Xing Zhao,Lu Bai,Rui-Ying Bao,Zheng-Ying Liu,Ming-Bo Yang,Wei Yang RSC Adv., 2017,7, 46297-46305
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David White,Sean R. Stowell Biomater. Sci., 2017,5, 463-474
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Ana G. Neo,Ana Bornadiego,Jesús Díaz,Stefano Marcaccini,Carlos F. Marcos Org. Biomol. Chem., 2013,11, 6546-6555
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Min Kim,Jae-Joon Lee,Tengling Ye,Panagiotis E. Keivanidis,Kilwon Cho J. Mater. Chem. C, 2020,8, 1686-1696
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J. Matthew Kurley,Phillip W. Halstenberg,Abbey McAlister,Stephen Raiman,Richard T. Mayes RSC Adv., 2019,9, 25602-25608
Additional information on (Z)-1,2-Bis(diphenylphosphino)ethene
Comprehensive Overview of (Z)-1,2-Bis(diphenylphosphino)ethene (CAS No. 983-80-2)
(Z)-1,2-Bis(diphenylphosphino)ethene, commonly referred to by its CAS number 983-80-2, is a highly specialized organophosphorus compound widely utilized in catalysis and material science. This compound, featuring a Z-configuration, is renowned for its ability to act as a bidentate ligand, forming stable complexes with transition metals. Its unique structure, comprising two diphenylphosphino groups attached to an ethene backbone, makes it invaluable in asymmetric synthesis and cross-coupling reactions, which are pivotal in pharmaceutical and agrochemical manufacturing.
Recent advancements in green chemistry have spurred interest in 983-80-2 due to its role in reducing hazardous waste in catalytic processes. Researchers are exploring its potential in sustainable catalysis, aligning with global trends toward eco-friendly industrial practices. The compound’s efficiency in palladium-catalyzed reactions, such as the Heck and Suzuki couplings, has made it a subject of numerous studies, particularly in optimizing reaction conditions to minimize energy consumption.
From an industrial perspective, (Z)-1,2-Bis(diphenylphosphino)ethene is critical in the production of fine chemicals and advanced materials. Its application extends to OLED technology, where it serves as a precursor for phosphorescent emitters, enhancing device efficiency. This connection to next-generation displays has amplified its relevance in tech-driven markets, addressing queries like “phosphine ligands in OLEDs” or “CAS 983-80-2 applications,” which frequently appear in scientific and patent literature searches.
Handling and storage of 983-80-2 require adherence to standard laboratory protocols, though it is not classified as a hazardous material under most regulatory frameworks. Its stability under inert atmospheres and compatibility with common organic solvents further bolster its practicality. For researchers seeking alternatives to traditional ligands, this compound’s steric and electronic tunability offers a versatile platform for innovation, as highlighted in recent publications on ligand design.
In summary, (Z)-1,2-Bis(diphenylphosphino)ethene (CAS 983-80-2) exemplifies the intersection of fundamental research and industrial application. Its adaptability to emerging fields like renewable energy and smart materials ensures its continued prominence in scientific discourse, answering pressing questions about efficient catalysis and sustainable chemical processes.
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