Cas no 627878-09-5 (Dichloro-[1,3-bis(diisopropylphenyl)imidazoliden-2-ylidene]palladium(II) dimer)
Dichloro-[1,3-bis(diisopropylphenyl)imidazoliden-2-ylidene]palladium(II) dimer Chemical and Physical Properties
Names and Identifiers
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- CX 42
- [(SIPr)PdCl2]2
- Umicore CX42
- UMicore CX42, 19% Pd, Product of UMicore
- Dichloro-[1,3-bis(diisopropylphenyl)imidazoliden-2-ylidene]palladium(II) dimer
- Dichloro(di-μ-chloro)bis[1,3-bis(2,6-diisopropylphenyl)-2-imidazolidinylidene]dipalladium(II)
- Palladium,bis[1,3-bis[2,6-bis(1-methylethyl)phenyl]-2-imidazolidinylidene]di-μ-chlorodichlorodi-, stereoisomer (9CI, ACI)
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- Inchi: 1S/2C27H39N2.4ClH.2Pd/c2*1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;;;;;;/h2*9-14,17-21H,15-16H2,1-8H3;4*1H;;/q;;;;;;2*+1/p-2
- InChI Key: VZZSKMKAUZLCEM-UHFFFAOYSA-L
- SMILES: [Pd]1(Cl[Pd](Cl1)(C1N(C2=C(C(C)C)C=CC=C2C(C)C)CCN1C1C(C(C)C)=CC=CC=1C(C)C)Cl)(C1N(C2C(C(C)C)=CC=CC=2C(C)C)CCN1C1=C(C(C)C)C=CC=C1C(C)C)Cl
Experimental Properties
- Melting Point: 309-315?°C
Dichloro-[1,3-bis(diisopropylphenyl)imidazoliden-2-ylidene]palladium(II) dimer Security Information
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Symbol:
- Signal Word:Warning
- Hazard Statement: H315-H319
- Warning Statement: P305+P351+P338
- Hazardous Material transportation number:NONH for all modes of transport
- WGK Germany:3
- Hazard Category Code: 36/38
- Safety Instruction: 26-37-46
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Hazardous Material Identification:
- Storage Condition:2-8°C
Dichloro-[1,3-bis(diisopropylphenyl)imidazoliden-2-ylidene]palladium(II) dimer Customs Data
- HS CODE:28439000
Dichloro-[1,3-bis(diisopropylphenyl)imidazoliden-2-ylidene]palladium(II) dimer Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| BAI LING WEI Technology Co., Ltd. | 1120794-250MG |
Umicore CX42, 19% Pd, Product of Umicore |
627878-09-5 | 250MG |
¥ 936 | 2022-04-26 | ||
| XI GE MA AO DE LI QI ( SHANG HAI ) MAO YI Co., Ltd. | 725439-1G |
CX42 |
627878-09-5 | Umicore | 1G |
¥561.16 | 2022-02-24 | |
| XI GE MA AO DE LI QI ( SHANG HAI ) MAO YI Co., Ltd. | 725439-250MG |
CX42 |
627878-09-5 | 250mg |
¥1046.33 | 2023-11-26 | ||
| SHANG HAI A LA DING SHENG HUA KE JI GU FEN Co., Ltd. | D196278-5g |
Dichloro-[1,3-bis(diisopropylphenyl)imidazoliden-2-ylidene]palladium(II) dimer |
627878-09-5 | 99.95% metals basis | 5g |
¥7209.90 | 2023-09-03 | |
| BAI LING WEI Technology Co., Ltd. | A011120794-250mg |
Dichloro-[1,3-bis(diisopropylphenyl)imidazoliden-2-ylidene]palladium(II) dimer |
627878-09-5 | N/A | 250mg |
¥936 | 2023-11-24 | |
| A2B Chem LLC | AG72442-250mg |
Umicore CX42 |
627878-09-5 | Umicore | 250mg |
$367.00 | 2024-04-19 | |
| A2B Chem LLC | AG72442-1g |
Umicore CX42 |
627878-09-5 | Umicore | 1g |
$941.00 | 2024-04-19 | |
| A2B Chem LLC | AG72442-5g |
Umicore CX42 |
627878-09-5 | 99.95% metals basis | 5g |
$2865.00 | 2024-04-19 |
Dichloro-[1,3-bis(diisopropylphenyl)imidazoliden-2-ylidene]palladium(II) dimer Related Literature
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Yiding Jiao,Liqun Kang,Jasper Berry-Gair,Kit McColl,Jianwei Li,Haobo Dong,Hao Jiang,Ryan Wang,Furio Corà,Dan J. L. Brett,Ivan P. Parkin J. Mater. Chem. A, 2020,8, 22075-22082
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J. Zagora,M. Vosla?,L. Schreiberová,I. Schreiber Phys. Chem. Chem. Phys., 2002,4, 1284-1291
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David White,Sean R. Stowell Biomater. Sci., 2017,5, 463-474
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Matthew J. Gaunt,Jinquan Yu,Jonathan B. Spencer Chem. Commun., 2001, 1844-1845
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Zhiyan Chen,Nan Wu,Yaobing Wang,Bing Wang,Yingde Wang J. Mater. Chem. A, 2018,6, 516-526
Additional information on Dichloro-[1,3-bis(diisopropylphenyl)imidazoliden-2-ylidene]palladium(II) dimer
Dichloro-[1,3-bis(diisopropylphenyl)imidazoliden-2-ylidene]palladium(II) Dimer (CAS No. 627878-09-5): A Versatile Catalyst in Modern Organic Synthesis
The Dichloro-[1,3-bis(diisopropylphenyl)imidazoliden-2-ylidene]palladium(II) dimer (CAS No. 627878-09-5) is a highly efficient and widely used N-heterocyclic carbene (NHC) palladium complex. This compound has gained significant attention in the field of organometallic chemistry and catalysis due to its exceptional stability, reactivity, and versatility in facilitating various cross-coupling reactions, such as Suzuki-Miyaura, Negishi, and Buchwald-Hartwig reactions. Its unique structural features, including the bulky diisopropylphenyl groups, contribute to its thermal stability and resistance to decomposition under harsh reaction conditions.
In recent years, the demand for sustainable and green chemistry solutions has driven researchers to explore catalysts like Dichloro-[1,3-bis(diisopropylphenyl)imidazoliden-2-ylidene]palladium(II) dimer. This compound aligns with the growing interest in atom-efficient and low-waste synthetic methodologies. Its ability to operate under mild conditions and with low catalyst loadings makes it an attractive choice for industries focused on pharmaceutical intermediates, agrochemicals, and advanced materials. Moreover, its compatibility with aqueous media and recyclable systems further enhances its appeal in modern synthetic applications.
The mechanistic insights into how NHC-palladium complexes like this dimer function have been a hot topic in academic and industrial research. Questions such as *"How does the steric hindrance of the NHC ligand affect catalytic activity?"* or *"What are the optimal conditions for maximizing yield in cross-coupling reactions?"* are frequently searched by chemists and engineers. The Dichloro-[1,3-bis(diisopropylphenyl)imidazoliden-2-ylidene]palladium(II) dimer provides a compelling case study for these inquiries, as its electron-rich NHC backbone and sterically demanding substituents play a critical role in stabilizing reactive intermediates and preventing unwanted side reactions.
Another area of interest is the scalability of reactions employing this catalyst. With the rise of flow chemistry and continuous manufacturing, researchers are investigating how Dichloro-[1,3-bis(diisopropylphenyl)imidazoliden-2-ylidene]palladium(II) dimer performs in these systems. Its robustness and compatibility with heterogeneous supports make it a candidate for immobilized catalyst systems, which are pivotal for large-scale industrial applications. Searches like *"Can NHC-palladium catalysts be reused in flow reactors?"* highlight the practical challenges and opportunities associated with this compound.
In summary, the Dichloro-[1,3-bis(diisopropylphenyl)imidazoliden-2-ylidene]palladium(II) dimer (CAS No. 627878-09-5) represents a cornerstone in modern catalytic chemistry. Its applications span from academic research to industrial processes, addressing key challenges in efficiency, sustainability, and cost-effectiveness. As the field evolves, this compound will likely remain at the forefront of innovations in organic synthesis and materials science.
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